Metallic alloys (no steels) |
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Metallic alloys (except steels & superconductors) Possible data sources: evitherm, CINDAS The thermal conductivity/diffusivity (and electrical conductivity) of metals is generally high. However, the thermal and partly mechanical treatment of the material may change their thermal conductivity/diffusivity. There is a relation between thermal conductivity and electric resistivity of metals called the Wiedemann-Franz-Lorenz law. Depending on the type of alloy there is a deviation between the theoretical and the real Lorenz number. For molten metals the theoretical Lorenz number is usually valid. In addition to the detailed chemical composition of metals, it is useful to know thermal pre-treatment of the material. Because hardness is also affected by thermal treatment this easily determined value is an additional help to estimate the thermal conductivity/diffusivity. Expansivity and density Emissivity and other infrared optical properties Spectral emissivity tends to decrease with increasing wavelength. In most instances, the spectral emissivity of metals tends to increase with temperature. Total emissivity tends also to increase with temperature but this is mainly due to the displacement of the spectrum toward short wavelengths than to the increase of the spectral emissivity with temperature. The spectral emissivity of a metal increases with surface roughness. The surface is considered to be "rough" if the imperfections are not much smaller than the wavelength. The theory says that the emissive properties of a metal are related to the electrical properties. With some simplifications and for wavelengths that are not too short, the normal spectral emissivity is proportional to the square root of electrical resistivity (Hagen-Rubens emissivity relation). The degree of oxidation has the greatest effect on the spectral emissivity of metals. If the oxide layer is thick, then the spectral emissivity of the surface is characterised by the oxide and is generally much higher than that of the underlying metal. If the oxide layer is thin, and so not opaque for all wavelengths, the value of spectral emissivity lies between that of the metal and the oxide and can depend strongly on the thickness of the oxide layer and wavelength value. |
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